Design of Low Alkali activator Geopolymer Concrete Mixtures

Authors

  • Eri Setia Romadhon Doctoral student of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang
  • Antonius Antonius Professor of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang
  • Sumirin Sumirin Lecturer of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

DOI:

https://doi.org/10.32832/astonjadro.v11i3.7484

Keywords:

mix design, low alkaline, activator geopolymer, concrete.

Abstract

This paper presents the results of research on the design of geopolymer concrete mixes. The main objective of this research is to develop an efficient and easy design of low-alkaline activator geopolymer concrete mixture, which until now has been the biggest obstacle in the use of geopolymer concrete. The variables reviewed were the amount of alkaline activator was quite low at 4%, room temperature and 60oC ratio of alkaline activator/fly ash (AAS/FA) were 0.35, 0.4, 0.5, 0.6. The test results show the parameters of geopolymer concrete with low alkali activator 4%, sodium silicate/sodium hydroxide ratio 2.5%, sodium hydroxide molarity 14M, type F fly ash and the discovery of the relationship model of compressive strength and the ratio of alkali activator/fly ash with a very high correlation as basic development of geopolymer concrete mix design. The design of the geopolymer concrete mix developed is easy because it is application-based and efficient because it only requires 4% alkaline activator.

Author Biographies

Eri Setia Romadhon, Doctoral student of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

Doctoral student of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

Antonius Antonius, Professor of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

Professor of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

Sumirin Sumirin, Lecturer of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

Lecturer of Civil Engineering, Department of Civil Engineering, Universitas Islam Sultan Agung (UNISSULA), Semarang

References

Al Bakri et al (2012)Effect of Na2SiO3/NaOH Ratios and NaOH Molarities on Compressive Strength of Fly-Ash-Based Geopolymer, A Journal ACI vol-.109,NO.5,september 2012

Alzeebaree ,í‡evik , Nematollahi,Sanjayan, Mohammedameen, Gülsan, (2019)Mechanical properties and durability of unconfined and confined geopolymer concrete with fiber reinforced polymers exposed to sulfuric acid, Construction and Building Materials 215 1015–1032

A. Naghizadeh, S.O. Ekolu (2019): Method for comprehensive mix design of fly ash geopolymer mortars, Construction and Building Materials 202 704–717

Amer Hassan, Mohammed Arif, M.Shariq (2019) Use of geopolymer concrete for a cleaner and sustainable environment – A review of mechanical properties and microstructure, Journal of Cleaner Production Maret 2019

Amir Ali Shahmansouri, Habib Akbarzadeh Bengar, Saeed Ghanbari (2020),: Compressive strength prediction of eco-efficient GGBS-based geopolymer concrete using GEP method Journal of Building Engineering doi: https://doi.org/10.1016/j.jobe.2020.101326.

"Andi Arham Adam*, Bayu Rahmat Ramadhan, and Shyama Maricar (2019) The Effects of Water to Solid Ratio, Activator to Binder Ratio, and Lime Proportion on the Compressive Strength of Ambient-Cured Geopolymer, Journal of the Civil Engineering Forum Vol. 5 No. 2 (May 2019)

Concrete"

Anuradha R, Sreevidya V, Venkatasubramani R, Rangan BV 2012. Modified guidelines for geopolymer concrete mix design using Indian standard. Asian J Civ Eng; 13(3):353–64.

Barbosa VFF, MacKenzie KJD(2003). Thermal behaviour of inorganic geopolymers and composites derived from sodium polysialate. Materials Research Bulletin ;38(2):319–31.

Bellum, Muniraj, Madduru, (2020) Exploration of mechanical and durability characteristics of fly ash"‘GGBFS based green geopolymer concrete, Springer Nature Switzerland AG

Benjamin C.McLellan, Ross P.Williams, Janine Lay, Arievan Riessen, Glen D.Corder (2011), Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement, Journal of Cleaner Production, Februari 2011

Bondar D, Ma Q, Soutsos M, Basheer M, Provis JL, Nanukuttan S. (2018) Alkali activated slag concretes designed for a desired slump, strength and chloride diffusivity. Constr Build Mater;190:191–9.

Bondar D, Nanukuttan S, Provis JL, Soutsos M. (2019) Efficient mix design of alkali activated slag concretes based on packing fraction of ingredients and paste thickness. J Clean Prod;218:438–49.

Chau-Khun Ma, Abdullah Zawawi Awang, Wahid Omar (2018, ) Structural and material performance of geopolymer concrete: A review Construction and Building Materials Vol. 186 oktober 2018

Davidovits, J., (1991). Geopolymer: inorganic polymer new materials. J. Therm. Anal. 37, 1633e1656.

Diaz EI, Allouche EN, Eklund S. (2010) Factors affecting the suitability of fly ash as source material for geopolymers. Fuel;89(5):992–6.

Diaz EI, Allouche EN, Vaidya S. (2011) Mechanical properties of fly-ash-based geopolymer concrete. ACI Mater J;108(3):300.

Ding Y, Shi C, Li N.( 2018) Fracture properties of slag/fly ash-based geopolymer concrete cured in ambient temperature. Constr Build Mater;190:787–95.

Ding, Dai, Jun Shi, (2016) Mechanical properties of alkali-activated concrete: A state-of-the-art review Construction and Building Materials 127 68–79

El-Hassan H, Ismail N. (2018) Effect of process parameters on the performance of fly ash/ GGBS blended geopolymer composites. Journal of Sustainable Cement-Based Materials.;7(2): 122–40.

Fatih Kantarcı, Ibrahim Türkmen, Enes Ekinci (2019): Optimization of production parameters of geopolymer mortar andconcrete: A comprehensive experimental study, Construction and Building Materials 228 116770

Ferdous M, Kayali O, Khennane A. (2013) A detailed procedure of mix design for fly ash based geopolymer concrete. Fourth Asia-Pacific Conference on FRP in Structures (APFIS), Melbourne, Australia.. p. 11–3.

Ferdous W, Manalo A, Khennane A, Kayali O. (2015) Geopolymer concrete-filled pultruded composite beams-Concrete mix design and application. Cement Concr Compos;58:1–13.

Fiki Riki Tambingon, Marthin D. J. Sumajouw, Steenie E. Wallah (2018) KUAT TEKAN BETON GEOPOLYMER DENGAN PERAWATAN TEMPERATUR RUANGAN, jurnal Sipil Statik september 2018, vol 6, No 9

Gum Sung Ryu et al (2013) The mechanical properties of fly ash-based geopolymer concrete with alkaline activators, Curtin University of Technology

Guohao Fang, Wing Kei Ho, Wenlin Tu, Mingzhong Zhang (2018): Workability and mechanical properties of alkali-activated fly ash-slag concrete cured at ambient temperature, Construction and Building Materials 172 476–487

Hadi MNS, Farhan NA, Sheikh MN. (2017) Design of geopolymer concrete with GGBFS at ambient curing condition using Taguchi method. Constr Build Mater;140 (Supplement C):424–31.

Hadi MNS, Zhang H, Parkinson S. (2019)Optimum mix design of geopolymer pastes and concretes cured in ambient condition based on compressive strength, setting time and workability. J Build Eng;23:301–13.

Hardjito D, Rangan BV. (2005) Development and properties of low-calcium fly ash-based geopolymer concrete. Curtin University of Technology

Hardjasaputra, Han A Lie, Cornelia, Gunawan, Surjaputra (2019) Study of mechanical properties of fly ash-based geopolymer concreteInternational Conference on Euro Asia Civil Engineering Forum IOP Conf. Series: Materials Science and Engineering 615

Harta, Meitha (2018), Analisis kebutuhan Batubara untuk Industri Domestik 2020-2035 Dalam Mendukung Kebijakan Domestik market Obligation Dan Kebijakan Energi Nasional, Jurnal Teknologi dan Batubara Vol 14, No 1 2018.

Herwani, Ivindra Pane , Iswandi Imran, Bambang Budiono(2018): Compressive Strength of Concrete Geopolymer Based on Flying Ash with Variable Sodium Hydroxide (NaOH) Solution Molarity, MATEC Web of Coferences 147 01004

Herwani et al (2018) Efektifityas Superplasticizer terhadap workability dan kuat tekan beton geopolimer, Jurnal Teknik Sipil Vol. 10, No. 2, Oktober 2018

Ishwarya, B.Singh, S.Deshwal, S.K.Bhattacharyya, (2018), Effect of sodium carbonate/sodium silicate activator on the rheology, geopolymerization and strength of fly ash/slag geopolymer pastes, Cemen Concrete composite, 8 April 2019.

Joseph B, Mathew G. (2012) Influence of aggregate content on the behavior of fly ash based geopolymer concrete. Scientia Iranica;19(5):1188–94.

Junaid MT, Kayali O, Khennane A, Black J. (2015) A mix design procedure for low calcium alkali activated fly ash-based concretes. Constr Build Mater;79:301–10.

Khalaj G, Hassani SES, Khezrloo A, Haratifar E-a-d. (2014) Split tensile strength of OPC-based geopolymers: application of DOE method in evaluating the effect of production parameters and their optimum condition. Ceramics International;40(7): 10945–52.

Lateef N.Assi, Kealy Carter, Edward Deaver, Paul Ziehl (2020) , Review of availability of source materials for geopolymer/sustainable concrete, Journal of Cleaner Production Volume 263, 1 August 2020, 121477

Li N, Shi C, Wang Q, Zhang Z, Ou Z. (2017) Composition design and performance of alkali-activated cements. Materials and Structures;50(3):178.

Li N, Shi C, Zhang Z, Zhu D, Hwang H-J, Zhu Y, et al. (2018) A mixture proportioning method for the development of performance-based alkali-activated slag-based concrete. Cement Concr Compos;93:163–74.

Lloyd N, Rangan V. (2010) Geopolymer concrete with fly ash. In: Proceedings of the second international conference on sustainable construction materials and technologies. UWM Center for By-Products Utilization;. p. 1493–504.

Lokuge W, Wilson A, Gunasekara C, Law DW, Setunge S. (2018) Design of fly ash geopolymer concrete mix proportions using Multivariate Adaptive Regression Spline model. Constr Build Mater;166:472–81.

Mahya Askarian et al (2018), Mechanical properties of ambient cured one-part hybrid OPC-geopolymer concrete, Construction and Building Materials 186 (2018) 330–337

M. Albitar, (2016) Mechanical, Durability and Structural Evaluation of Geopolymer Concretes, School of Civil, Environmental and Mining Engineering, The University of Adelaide, Australia oktober

M. Albitar, M.S. Mohamed Ali, P. Visintin b, M. Drechsler (2017), Durability evaluation of geopolymer and conventional concretes,Construction and Building Materials 136 (2017) 374–385

M.W. Ferdous, O. Kayali and A. Khennane (2013) : A Detailed Procedure of Mix design For Fly Ash Based Geopolymer Concrete, Fourth Asia-Pacific Conference on FRP in Structures (APFIS 2013)11-13 December 2013, Melbourne, Australia

Mehta A, Siddique R, Singh BP, Aggoun S, Åagod G, Barnat-Hunek D. (2017) Influence of various parameters on strength and absorption properties of fly ash based geopolymer concrete designed by Taguchi method. Constr Build Mater;150 (Supplement C):817–24.

Muhammad N.S. Hadi ⇑, Nabeel A. Farhan, M. Neaz Sheikh (2017),Design of geopolymer concrete with GGBFS at ambient curing condition using Taguchi method Construction and Building Materials 140 (2017) 424–431

Muhammad N.S. Hadi, Haiqiu Zhang, Shelley Parkinson (2019): Optimum mix design of geopolymer pastes and concretes cured in ambient condition based on compressive strength, setting time and workability, Journal of Building Engineering 23 (2019) 301–313

Muhammad Zahid et al (2018), Statistical modeling and mix design optimization of fly ash based engineered geopolymer composite using response surface methodology, Cleaner Production, mei 2018

Ning Li, Caijun Shi, Zuhua Zhang, Deju Zhu, Hyeon-Jong Hwang, Yuhan Zhu, (2018), A mixture proportioning method for the development of performance-based alkaliactivated slag-based concrete, Cement and Concrete Composites (2018), doi: 10.1016/j.cemconcomp.2018.07.009.

Ning Li, Caijun Shi,Zuhua Zhang, Hao Wang, Yiwei Liu (2019): A review on mixture design methods for geopolymer concrete Composites Part B 178 (2019) 107490

Olivia M, Nikraz H. (2012) Properties of fly ash geopolymer concrete designed by Taguchi method. Materials and Design 2012;36:191–8.

P. Chindaprasirt, T. Chareerat, V. Sirivivatnanon (2007) : Workability and strength of coarse high calcium fly ash geopolymer, Cement & Concrete Composites 29 (2007) 224–229

Partogi H. Simatupang, Iswandi Imran, Ivindra Pane, Bambang Sunendar (2015) : On the Development of a Nomogram for Alkali Activated Fly Ash Material (AAFAM) Mixtures J. Eng. Technol. Sci., Vol. 47, No. 3, 2015, 231-249

Pavithra P, Srinivasula Reddy M, Dinakar P, Hanumantha Rao B, Satpathy BK, Mohanty AN. (2016) A mix design procedure for geopolymer concrete with fly ash. J Clean Prod;133:117–25.

Thumrongvut J, Chindaprasirt P. (2018) A mix design procedure for alkali-activated high-calcium fly ash concrete cured at ambient temperature. Ann Materials Science & Engineering 2018:1–13.

Puput Risdanareni et al (2015), Effect of Alkaline Activator Ratio to Mechanical Properties of Geopolymer Concrete with Trass as Filler, Applied Mechanics and Materials Vols. 754-755 (2015) pp 406-412 Submitted: 06.01.2015

Purwanto, Ay Lie Han,Nuroji, and Januarti Jaya Ekaputri (2018)The influence of molarity variations to the mechanical behavior of geopolymer concrete, MATEC Web of onferences 195, (2018)

Qingwei, Han Zhui, Haoyu, Haiyang, Minming (2018) : Application of Respone Surface Methodology in Optimation of Fly Ash geopolymer concrete, Romanian Journal of Materials 2018, 48 (1), 45 - 52

Rafeet A, Vinai R, Soutsos M, Sha W. (2017) Guidelines for mix proportioning of fly ash/ GGBS based alkali activated concretes. Constr Build Mater 2017;147(Supplement C):130–42.

Rangan B. (2007) Concrete construction engineering handbook. CRC Press; 2007.

"Rattanasak dan Chindaprasirt (2009) Influence of NaOH solution on the synthesis of fly ash geopolymer, Minerals Engineering 22 (2009) 1073–1078

Reddy MS, Dinakar P, Rao BH. (2018) Mix design development of fly ash and ground granulated blast furnace slag based geopolymer concrete. J Build Eng 2018;20: 712–22.

Reddy Bellum et al (2020)Exploration of mechanical and durability characteristics of fly ash"‘GGBFS based green geopolymer concrete, SN Applied Sciences (2020) 2:919

Remigildus Cornelis1, Henricus Priyosulistyo,Iman Satyarno,Rochmadi (2019: Workability and Strength Properties of Class C Fly Ash-Based Geopolymer Mortar MATEC Web of Conferences 258, 0100 SCESCM

Retno Damayanti, (2018) : Abu Batubara Dan Pemanfaatannya, TinjauanTeknis Karakteristik secara Kimia dan Toksikologinya, Jurnal Tekniknologi Mineral dan Batubara volume 14, no. 3 September 2018.

Sing NT, FS J. (2013) Development of a mix design methodology for high-performance geopolymer mortars. Struct Concr 2013;14(2):148–56.

Sun Keke, Peng Xiaoqin, Wang Shuping, Zeng Lu (2019): Design method for the mix proportion of geopolymer concrete based on the paste thickness of coated aggregate, Journal of Cleaner Production 232 (2019) 508e517

Thomas, S. Peethamparan, (2015) Alkali-activated concrete: engineering properties and stress–strain behavior, Constr. Build. Mater. 93 (2015) 49–56.

Xu, H., van Deventer, J.S.J., 2000. The geopolymerisation of alumino-silicate minerals. International Journal of Mineral Processing. 59, 247e266.

Yang C, Yang K, Pan Q, Chen K, Zhu X. (2017) Parameter and design method for alkali-activated slag concrete mix. Journal of Civil, Architectural and Environmental Engineering 2017;39(4):122–7 [In Chinese].

Yifeng Ling, Kejin Wang,Xuhao Wang, Sudong Hua (2019): Effects of mix design parameters on heat of geopolymerization, set time,and compressive strength of high calcium fly ash geopolymer Construction and Building Materials 228 (2019) 116763

Y.H. Mugahed Amran, Rayed Alyousef, Hisham Alabduljabbar, Mohamed El-Zeadani (2020), Clean production and properties of geopolymer concrete; A review, Journal of Cleaner Production, Volume 251, 1 April 2020, 119679

Zain MFM, Abd SM. (2009) Multiple regression model for compressive strength prediction of high performance concrete. J. Applied Surface Science2009;9(1):155–60.

Published

2022-09-23

How to Cite

Romadhon, E. S., Antonius, A., & Sumirin, S. (2022). Design of Low Alkali activator Geopolymer Concrete Mixtures. ASTONJADRO, 11(3), 627–638. https://doi.org/10.32832/astonjadro.v11i3.7484

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Articles